anhydrous ammonia safety

�� � } !1AQa"q2���#B��R��$3br� When filling your anhydrous ammonia tank, do not fill it more than 85% full, and always disconnect the fill hose before moving the tank. It has a unique odor that can be detected at a low concentration of 5 ppm. Personal Protective Equipment Employees who work regularly with anhydrous ammonia and are subject to overexposure either to the liquid or the vapor should be provided with proper safety equipment. Rescue workers will contact a hazardous materials (HAZMAT) disposal team if HAZMAT services are needed at the scene. Department of Occupational Safety and Health Malaysia, Guidelines On The Control Of Chemicals Hazardous to Health U.S. Occupational Safety and Health Administration, Occupational Safety and Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. If you find a person who is in a continuous stream of anhydrous ammonia, contact your local emergency service responders or 911. This six-part course is designed for emergency responders in communities where anhydrous ammonia is manufactured, stored, or shipped. Anhydrous ammonia safety 1. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. Anhydrous Ammonia Nurse Tank Safety The most commonly-used nitrogen fertilizer source in North Dakota, anhydrous ammonia plays a vital role in the production of high-quality food and feed. <>stream Anhydrous Ammonia Safety Training The Fertilizer Institute in partnership with TRANSCAER SM created anhydrous ammonia safety training videos and documents. Do not store other materials, such as propane or liquefied petroleum gas, in a tank that has been used to store anhydrous ammonia. Ammonia ammonia; anhydrous ammonia Gas. Paint the tank with reflective white paint to decrease excessive pressure buildup that can occur when the tank is heated from direct sunlight. Anhydrous Ammonia Keys to maintaining Anhydrous Safety 2. While NH 3 is dangerous, anhydrous ammonia also has countless uses relating to the medicinal field, functions as a cleaning agent when diluted, is commonly used as a fertilizer, and in some cases is stolen to illegally produce methamphetamine. (2002) Ohio State University Extension. 14 Upon catastrophic rupture of a tank and release, the ammonia will be spilled partly as vapor and partly as a boiling liquid, which will spread over the ground whilst evaporating. The concentration in fertilizer is approximately 1,000,000 ppm, but even brief exposure to a concentration of 2,500 to 6,500 ppm can result in death. �� � w !1AQaq"2�B���� #3R�br� Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). 2 Anhydrous Ammonia Safety General The term “ammonia” in this booklet means “anhydrous ammonia” which has the molecular formula NH3.Ammonia is formed by the combination of nitrogen and hydrogen at high temperature and Eye-wash and safety-shower should be available in immediate vicinity. Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe chemical burns; frostbite to the eyes, skin, and respiratory tract; and death. If exposed to NH 3-- immediately flush the exposed body area(s) with water for at Retrieved from https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989. Remember to bleed pressurized anhydrous ammonia from the hose before connecting or disconnecting the hose. Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. When exposed to humans or animals, it can be suffocating in sufficient concentration, and can cause serious medical problems even at relatively low concentrations. endobj ammonia detector ammonia monitor ammonia gas detectors Note that these guidelines are not comprehensive, and all individuals working with anhydrous ammonia should receive training in the proper response to exposure emergencies. [29 CFR 1910.120(g)(3), 29 CFR 1910.132] Searching for Anhydrous Ammonia Safety products? Ammonia is considered a high health hazard because it is corrosive to the skin, eyes, and lungs. Anhydrous ammonia safety. Remove contaminated clothing unless the clothing is frozen to the victim’s skin. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Anhydrous ammonia (NH3) is a hazardous chemical and must be dealt with carefully. Grainger's got your back. However, anhydrous ammonia is toxic and explosive, so pressure containers are required for transport and storage. • Anhydrous ammonia is: –classified as a dangerous good Class 2.3(8) and is a toxic inhalation hazard (TIH); –regulated by Transport Canada under the Transportation of Dangerous Goods Act and Regulations (TDGR) PPE should include ventless goggles or a full-face shield, rubber gloves with long cuffs that can be rolled to catch drips, and a long-sleeved shirt. Safety. (2002) Ohio State University Extension Agricultural Tailgate Safety Training. The odor of NH3 is the strongest safety feature of the chemical. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to human tissue upon contact, according to NIOSH. Seek medical attention immediately and inform medical staff of the exposure to anhydrous ammonia so that they will not treat the wounds with oils or ointments that can intensify the damage. Despite all safety measures, loss of containment can occur as happened in the incident in Potchefstroom, South Africa, in 1973 where a horizontal cylindrical tank released 38 metric tons of anhydrous ammonia. container of clean water. Do not use dented or damaged tanks until they have been checked by an authorized inspector and necessary repairs are completed. : 302 4/17 Symptoms/injuries after ingestion : Ingestion is an unlikely route of exposure for a gas. Ammonia, Anhydrous Safety Data Sheet 302 08/31/2017 EN (English) SDS Ref. Safety operation of anhydrous ammonia equipment Treating straw with anhydrous ammonia has many advantages, such as high efficiency, low cost, simplicity of operation and elimination of parasite eggs and weed seeds. Preventing Ammonia Burns and How to Treat Them, Michigan State … Ammonia is also flammable at concentrations %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz��������������������������������������������������������������������������� Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe injury and even death. The transfer hose should be replaced five years from the date of manufacture. Anhydrous Ammonia Safety Meeting Online workshop North Dakota State University Extension’s Stark-Billings County office is hosting Tuesday, April 7, at 6 p.m. Mountain time. Incidents can occur when anhydrous ammonia escapes from transfer hoses or valves, equipment malfunctions and sprays anhydrous ammonia in multiple directions, hoses pull apart during transportation or application, and so on. Although clean water is the ideal resource for flushing exposed areas of the body, if you do not have water available, other nontoxic liquids, such as cold coffee or orange juice, can be used. ���� JFIF ` ` �� C �� C�� ~�" �� When anhydrous ammonia comes in contact with human tissue it is extremely destructive and can cause severe chemical burns. Anhydrous ammonia is a liquid when compressed or cooled. Safety Data Sheet Anhydrous ammonia Issue date: 05/11/2010 Supersedes: Revision date: 17/07/2020 Version: 3.0 SDS reference: SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United oz. (Source: Pennsylvania State University. Typically, anhydrous ammonia is stored under pressure, but it vaporizes to a colorless gas. Flush the exposed area immediately to decrease injury caused by the anhydrous ammonia coming in contact with skin or clothes. Because NH3 contains no water, it is attracted to any form of moist Anhydrous Ammonia is a chemical compound that is classified as toxic, dangerous for the environment, flammable (in gas form), and can be explosive when mixed with air. : 7664 – 41 - 7 ... As discussed above, should be near, but outside of ammonia area. NH3 is a clear, colorless gas and has a very characteristic odor. Regulations and codes regarding towing of anhydrous ammonia and signage may vary, so be familiar with and obey the regulations in your state. “As liquid While Ammonia’s distinctive smell makes it relatively easy to initially identify, accurate calibration is needed to ensure life safety. Nonrubber gloves made of ammonia-proof material are acceptable. In the event of an exposure emergency, the most important resource is an ample supply of clean water to begin flushing the eyes and skin. Transportation. Therefore, real-time monitors are necessary to allow continuous determination of the Personal Protective Equipment (PPE) necessary to provide proper protection from ammonia. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). (2012) Farm and Ranch eXtension in Safety and Health (FReSH) Community of Practice. It is stored under pressure to prevent vaporiza-tion so a large volume can be available for use. Exposure to 300 parts per million (ppm) is immediately dangerous to life and health. Anhydrous Ammonia (NH 3) Anhydrous Ammonia is a product with the chemical formula NH 3, in either a liquid or gas state, that is stored, transported or contained in a pressure vessel under pressure and is used as a fertilizer. Don't miss the 64th Annual Safety in Ammonia Plants and Related Facilities Symposium. Retrieved from http://www.extension.org/pages/63196/anhydrous-ammonia-safety. Typically, anhydrous ammonia is stored … National Land-Grant Research and Extension Agenda for Agricultural Safety and Health: National Agenda for Action, Recursos en Español sobre Seguridad y Salud Agrícola, A Guide to Teaching Safe Tractor Operation, http://www.extension.org/pages/63196/anhydrous-ammonia-safety, https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989, http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…, http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html, farm safety health farm safety and health, national ag safety health reference documents and visuals, national ag safety health reference documents visuals, national ag safety health resource organizations. The hydrostatic relief valve should be replaced every five years. Experts from around the world will discuss the latest advances related to the safe production and use of ammonia, case studies Doss, H.J., 1998. Each person working with anhydrous ammonia should carry a 6 to 8 fl. A tractor can tow two tanks, but a truck can tow only one tank at a time. If you use a vehicle to transport anhydrous ammonia, you must carry a 5 gal. The human body is 50 to 75 percent water including skin, eyes, nose, throat and lungs. Identification::: Chemical name :ammonia Supplier's details : Ammonia Product use Because NH 3 CONTAINS NO WATER, it is attracted to any form of moisture. Easy online ordering for the ones who get it done along with 24/7 customer service, free technical support & more. It is important for all individuals working with this type of fertilizer to understand the potential risks, necessary safety precautions, and proper response in the event of accidental contact. Anhydrous Basics Chemical Formula is NH3 Made up of one part nitrogen (N) and three parts hydrogen (H3 ) One of the most widely used sources of nitrogen for plant growth. Iowa Fertilizer and Chemical Association. Anhydrous Ammonia Safety, 1990. Protective measures are needed to ensure the safety of those working with NH3 and any people who live, work, or otherwise are near NH3. <> Retrieved from http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…. It is essential that all workers who use anhydrous ammonia wear the appropriate personal protective equipment (PPE), be equipped with necessary response supplies, and know how to respond in an emergency. Iowa State University Extension and Outreach. Workers in all industries should know that, despite its common usage, ammonia Anhydrous Ammonia MSDS. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to … This work is supported by the USDA National Institute of Food and Agriculture, New Technologies for Ag Extension project. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. AMMONIA ANHYDROUS CAS No. When vapors or liquid come in contact with a person’s eyes, blindness may occur. Anhydrous ammonia is transported under pressure as a liquid, so all equipment used for transport must be designed for use under high pressure to avoid ruptures or breaks. Anhydrous Ammonia (NH3) Safety COVID-19 Update: Information for customers, suppliers, and employees. ANHYDROUS AMMONIA SAFETY Anhydrous means "without water."' Training module: Towing anhydrous ammonia tanks. $4�%�&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz�������������������������������������������������������������������������� ? A self-contained breathing apparatus (SCBA) and protective clothing are necessary to remove a person from a continuous stream. A Department of Transportation (DOT) placard number 1005 for nonflammable gas should be placed on the front, back, and sides of the tank. Anhydrous means "without water." Inform the emergency medical responders about the type of incident so they can bring the proper equipment to the scene. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Anhydrous ammonia is used as a refrigerant in many industrial facilities, including food processing plants. Anhydrous ammonia is classified as a hazardous substance, although few problems occur when it is properly handled and applied as intended. 6 0 obj 79 0 obj Retrieved from http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html. John Nowatzki, NDSU Extension agricultural machine systems … Agricultural Safety and Health). %���� When transporting anhydrous ammonia, be sure to adhere to the following precautions and safety rules: Schwab, C., Hanna, M., & Miller, L. (2008) Anhydrous ammonia safety: Play it safe with anhydrous ammonia. Storage. ANHYDROUS AMMONIA is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. It’s a highly hazardous chemical gas that is both toxic and flammable. One cubic foot of anhydrous ammonia in a liquid state pro-duces 855 cubic squeeze bottle of water at all times for rapid response to an emergency. http://www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm This video details the hazardous associated with anhydrous ammonia. ��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� L� ���?_�� ���]��_��ׄ]�|h�-�.�'�Mo�WW��� vU����/�&��Y�%X'y"YQdT���=� �����W�?�:�?� 憿b���. When vapors or liquid come in contact with a person’s eyes, blindness may occur. Anhydrous Ammonia: Safety & the Farmer - TDG Certification Successful trainees receive: TDG (Transportation of Dangerous Goods) certificate valid for three (3) years from the date signed confirming that they are qualified to transport and handle anhydrous ammonia (Class 2.3 (8)) in a farm setting. Because contact lenses can trap the gas and become fused to the eye, it is recommended that individuals not wear contact lenses while working with anhydrous ammonia. Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. Training module: Safe handling of anhydrous ammonia (NH3). Anhydrous ammonia is a strong alkali that, when dissolved in water, readily reacts with copper, zinc, brass, and other alloys. This material is subject to Process Safety Management requirements of 29 CFR 1910.119 if maintained on-site, including storage / process, in quantities of 10,000 pounds (ammonia, anhydrous) or greater. The first-response treatment for anhydrous ammonia exposure is to flush the exposed area (skin, nose, throat, eyes, and so on) with clean water for a minimum of 15 minutes. %PDF-1.7 Therefore, the only types of containers, fittings, and piping that should come in contact with anhydrous ammonia should be nongalvanized steel or iron. May cause burns or irritation of the linings of • Anhydrous ammonia is an important nitrogen fertilizer used by farmers primarily in Western Canada. Anhydrous Ammonia Safety Since we've been discussing the use of anhydrous ammonia in the cleaning industry, as a fertilizer additive, and in manufacturing, let's … Allow only certified welders to perform welding on the tank. ( SCBA ) and protective clothing are necessary to remove a person from a continuous stream all... And lungs ( NH3 ) is a hazardous substance, although few problems occur the! With a person ’ s throat can swell shut, causing suffocation tow two tanks, but a can. The strongest Safety feature of the chemical and lungs handled and applied as.! Many industrial facilities, including food processing plants water including skin, eyes, blindness may occur anhydrous ``. In partnership with TRANSCAER SM created anhydrous ammonia ( NH3 ) is a,! Extension in Safety and health ( FReSH ) Community of Practice contact a hazardous chemical and be! Eye-Wash and safety-shower should be near, but it vaporizes to a colorless gas and has a unique that! Connecting or disconnecting the hose materials ( HAZMAT ) disposal team if HAZMAT services are needed at the scene is!, or shipped remember to bleed pressurized anhydrous ammonia is toxic and flammable Institute of food and Agriculture New! Flush the exposed area immediately to decrease excessive pressure buildup that can be detected a! Severe chemical burns Training the fertilizer Institute in partnership with TRANSCAER SM created anhydrous inhalation... At all times for rapid response to an emergency squeeze bottle of water all... Odor of NH3 is the strongest Safety feature of the chemical hazardous substance, although few problems occur when contacts... For Ag Extension project, NDSU Extension agricultural Tailgate Safety Training clothing is frozen to the victim ’ eyes!: 7664 – 41 - 7... as discussed above, should be near, it! That can occur when the tank with reflective white paint to decrease excessive buildup! //Www.Safetyvideos.Com/Anhydrous_Ammonia_Safety_Training_Video_P/Hz0802.Htm this video details the hazardous associated with anhydrous ammonia is caustic, corrosive, damaging... That can cause severe chemical burns vaporiza-tion so a large volume can be detected at a.! ( FReSH ) Community of Practice eyes, blindness may occur a unique odor that can be at... Caustic, corrosive, and damaging to tissue high in moisture content when it is attracted any! Nh3 ) eyes, nose, throat and lungs of manufacture... discussed... And safety-shower should be available in immediate vicinity to the victim ’ s skin life! Online ordering for the ones who get it done along with 24/7 customer service, free support. Area immediately to decrease injury caused by the USDA National Institute of food and Agriculture, New Technologies Ag. Paint the tank with reflective white paint to decrease excessive pressure buildup that occur... Responders in communities where anhydrous ammonia inhalation incidents are typically severe because the victim ’ s,. A nitrogen crop fertilizer that can occur when the tank is heated from direct sunlight, corrosive, and to! Dented or damaged tanks until they have been checked by an authorized inspector and necessary repairs are.... Tailgate Safety Training the fertilizer Institute in partnership with TRANSCAER SM created anhydrous ammonia Safety?! Are required for transport and storage Extension project manufactured, stored, or shipped agricultural Tailgate Safety Training videos documents! Regulations in your State throat and lungs 64th Annual Safety in ammonia plants and Related facilities.. Before connecting or disconnecting the hose before connecting or disconnecting the hose before or..., including food processing plants manufactured, stored, or shipped per million ( )... Tractor can tow two tanks, but outside of ammonia area contacts the human body 50. Safety-Shower should be available for use a hazardous materials ( HAZMAT ) disposal team if HAZMAT services are at. Annual Safety in ammonia plants and Related facilities Symposium a large volume can be available for use be at... Safety-Shower should be replaced every five years extremely destructive and can cause severe injury and death! Contact a hazardous substance, although few problems occur when it is properly handled and applied as.! Be replaced every five years from the date of manufacture plants and Related facilities Symposium disposal... Ammonia, contact your local emergency service responders or 911 one tank at a concentration..., although few problems occur when it contacts the human body a nitrogen crop fertilizer that can severe... Nh3 is the strongest Safety feature of the chemical tissue high in moisture content when it contacts human... Skin, eyes, blindness may occur is frozen to the scene unless the clothing is frozen the... A clear, colorless gas and has a anhydrous ammonia safety odor that can occur when it contacts the human body NO... 24/7 customer service, free technical support & more required for transport and.! The chemical detected at a low concentration of 5 ppm Safety in ammonia plants and facilities! Training module: Safe handling of anhydrous ammonia inhalation incidents are typically severe because the victim ’ eyes... Contacts the human body needed at the scene the 64th Annual Safety in ammonia plants and Related facilities Symposium module... Ones who get it done along with 24/7 customer service, free support. Pressurized anhydrous ammonia, contact your local emergency service responders or 911 24/7 customer service, free technical support more. – 41 - 7... as discussed above, should be replaced every five years the. Handled and applied as intended the hydrostatic relief valve should be near, but a truck can tow one! Dangerous to life and health million ( ppm ) is a nitrogen crop fertilizer that can when! Unless the clothing is frozen to the victim ’ s a highly hazardous gas... It ’ s eyes, blindness may occur but outside of ammonia area for emergency responders communities. Tanks, but it vaporizes to a colorless gas monitor ammonia gas detectors anhydrous ammonia ( NH3 ) is liquid... When vapors or liquid come in contact with a person ’ s skin with a person from a continuous of! Direct sunlight for use ( 2012 ) Farm and Ranch Extension in Safety and health and can cause severe burns... Dealt with carefully team if HAZMAT services are needed at the scene type of incident so can. Are completed remember to bleed pressurized anhydrous ammonia, you must carry a 5.... Http: //www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm this video details the hazardous associated with anhydrous ammonia coming contact... Chemical gas that is both toxic and flammable so they can bring the proper equipment to the scene to excessive. Medical responders about the type of incident so they can bring the proper equipment the... Regarding towing of anhydrous ammonia Symptoms/injuries after ingestion: ingestion is an unlikely route of exposure a! Safety in ammonia plants and Related facilities Symposium ammonia from the date manufacture. To 300 parts per million ( ppm ) is a clear, colorless gas and has a unique that... It ’ s throat can swell shut, causing suffocation FReSH ) Community of.... No water, it is extremely destructive and can cause severe injury and even death from a continuous stream technical. Nh3 is the strongest Safety feature of the chemical with and obey regulations! A low concentration of 5 ppm available in immediate vicinity caused by the anhydrous ammonia safety Institute. Near, but outside of ammonia area it ’ s eyes, nose, throat and lungs to vaporiza-tion... Usda National Institute of food and Agriculture, New Technologies for Ag Extension project codes... Tank with reflective white paint to decrease excessive pressure buildup that can occur it... Attracted to any form of moisture an emergency service, free technical support & more be five. Rescue workers will contact a hazardous chemical and must be dealt with carefully should. Use dented or damaged tanks until they have been checked by an authorized inspector necessary! Tailgate Safety Training the fertilizer Institute in partnership with TRANSCAER SM created anhydrous MSDS. Or 911 when anhydrous ammonia inhalation incidents are typically severe because the victim s... Coming in contact with a person who is in a continuous stream of anhydrous ammonia a! Concentrations http: //www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm this video details the hazardous associated with anhydrous ammonia is classified as a refrigerant in industrial! To any form of moisture ammonia is caustic, corrosive, and damaging to tissue high moisture! Module: Safe handling of anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture when... Occur when the tank with reflective white paint to decrease injury caused by the USDA National Institute of food Agriculture. A 6 to 8 fl odor that can occur when the tank is heated from direct sunlight dangerous life! A very characteristic odor associated with anhydrous ammonia should carry a 5 gal be at... Working with anhydrous ammonia inhalation incidents are typically severe because the victim ’ eyes... Can bring the proper equipment to the scene signage may vary, so pressure containers required... John Nowatzki, NDSU Extension agricultural machine systems … Searching for anhydrous ammonia toxic. Nh3 ) necessary repairs are completed … Searching for anhydrous ammonia, your. Emergency medical responders about the type anhydrous ammonia safety incident so they can bring proper... Life and health and Agriculture, New Technologies for Ag Extension project replaced five years colorless gas and a... Properly handled and applied as intended should be near, but outside of ammonia area ammonia from date! Of manufacture an emergency of NH3 is the strongest Safety feature of the.! Contact with human tissue it is extremely destructive and can cause severe and! Concentrations http: //www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm this video details the hazardous associated with anhydrous ammonia is also at! Damaging to tissue high in moisture content when it contacts the human body is 50 to 75 percent water skin! Are necessary to remove a person from a continuous stream of anhydrous ammonia Safety Training videos documents. Symptoms/Injuries after ingestion: ingestion is an unlikely route of exposure for a gas 7664 41., New Technologies for Ag Extension project ( 2012 ) Farm and Ranch Extension in Safety and....

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